Oxygen Rocks

Other than hydrogen and helium, oxygen is the most common element in the universe (followed closely by carbon). Hydrogen and helium condensed from light itself during the Big Bang, but everything else is made in the core of stars. Three helium atoms make carbon, and four helium atoms make oxygen.


The Earth’s crust and mantle are made of rocks, which are made of minerals. Each mineral is a different chemical compound whose atoms are arranged in a regular 3D crystal “lattice.” To a good approximation, rocks are composed of oxygen atoms that are crammed as close together as possible, and all the other elements occupy just the little void spaces between the oxygen spheres!


Think about cramming a lot of ping-pong balls into a box. Each ball will be surrounded by exactly six others, which will just touch (a). Once the bottom of the box is filled, the next layer is offset a bit so that each ball rests in the space made by three balls underneath (b). The most efficient way to pack spheres is to stagger the layers in sets of three (c). This is called “cubic closest packing,” and this is how oxygen is arranged to form the solid crust of the Earth.  The little void spaces in between the closely-packed oxygen atoms are filled with silicon, aluminum, calcium, sodium, magnesium, iron, and all the other common elements.






When the Earth was young, all of the oxygen was chemically bound up like this. The only oxygen in the early atmosphere was bound up too, mostly as CO2 and H2O. The early atmosphere was what chemists call a “reducing” environment. There was virtually no free oxygen in the air for the first couple of billion years of Earth’s history, but there were other gases that couldn’t exist today: ammonia, hydrogen, methane, hydrogen sulfide. It would have been toxic, but there were no living things at the surface to be harmed. 


Not until at least a billion years after Earth’s formation did the first photosynthetic microbes in the oceans begin to free oxygen from its chemical bonds. The biggest chemical change in geologic history had begun — the oxidation of the oceans, atmosphere, and even the Earth’s crust!